{
  "schema_version": "1.0.0",
  "dataset_status": "validated",
  "dataset_version": "2026-08-09",
  "updated_at": "2026-08-09",
  "scope": {
    "topic": "repeated_hot_water_extraction_of_roasted_ground_coffee",
    "language": "ja",
    "product_note": "市販ドリップバッグを2回・3回使った全製品共通の実測値ではなく、関連する査読研究とSCAA/SCAE Gold Cup抽出基準を分けて表示する。"
  },
  "sources": [
    {
      "id": "lang_2013",
      "publisher": "American Chemical Society",
      "title": "Quantitative studies on roast kinetics for bioactives in coffee",
      "published_at": "2013-11-25",
      "url": "https://doi.org/10.1021/jf403846g",
      "record_url": "https://pubmed.ncbi.nlm.nih.gov/24274681/",
      "source_type": "peer_reviewed_article",
      "applicability": "specific_compound_migration",
      "rights_note": "論文の数値的事実を要約。図表は転載せず独自表示する。",
      "retrieved_at": "2026-08-09"
    },
    {
      "id": "sca_gold_cup_2012",
      "publisher": "World Coffee Events / Specialty Coffee Association of Japan",
      "title": "2012 World Brewers Cup Rules and Regulations",
      "edition_year": 2012,
      "document_version": "2011.09.09",
      "url": "https://www.scaj.org/wp-content/uploads/2013/09/2012-WORLD-BREWERS-CUP-RULES-AND-REGULATIONS-VERSION-2012.09.09.pdf",
      "sha256": "43c29699e395e47caaf50dbfc62bd2b5d40b0664e246f849c1def821e812b3bc",
      "source_type": "technical_standard",
      "applicability": "filter_brewing_gold_cup_benchmark",
      "rights_note": "公式大会規則に記載されたGold Cup Standardの抽出収率を要約。発行日は推測せず、2012年版と文書内のVersion 2011.09.09を分けて記録し、原PDFは転載しない。",
      "retrieved_at": "2026-08-09"
    },
    {
      "id": "batali_2020",
      "publisher": "Journal of the Science of Food and Agriculture",
      "title": "Sensory and monosaccharide analysis of drip brew coffee fractions versus brewing time",
      "published_at": "2020-02-07",
      "url": "https://doi.org/10.1002/jsfa.10323",
      "record_url": "https://coffeecenter.ucdavis.edu/faculty-research/publications",
      "explainer_url": "https://sca.coffee/sca-news/25-magazine/issue-11/less-strong-more-sweet-byd7r",
      "source_type": "peer_reviewed_article",
      "applicability": "single_brew_time_fractions_not_second_use",
      "rights_note": "Table 2の数値的事実を3時点へ再構成。原図は転載しない。",
      "retrieved_at": "2026-08-09"
    },
    {
      "id": "maiyah_2026",
      "publisher": "Food Chemistry: X",
      "title": "Impact of roasting levels and brewing cycles on bioactive compounds in spent coffee grounds",
      "published_at": "2026-02-16",
      "url": "https://doi.org/10.1016/j.fochx.2026.103661",
      "record_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC12933743/",
      "license_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
      "source_type": "peer_reviewed_article",
      "applicability": "sequential_brewing_residue_analysis",
      "rights_note": "残渣分析の結論を要約。飲料中の量へ変換しない。",
      "retrieved_at": "2026-08-09"
    }
  ],
  "compound_migration": {
    "source_id": "lang_2013",
    "water_to_coffee_ratio_operator": "greater_than",
    "water_to_coffee_ratio_threshold": 16,
    "migrated_to_first_brew_percent_min": 90,
    "quality": "reported_threshold",
    "compounds": [
      { "id": "caffeine", "label_ja": "カフェイン" },
      { "id": "trigonelline", "label_ja": "トリゴネリン" },
      { "id": "caffeoylquinic_acids", "label_ja": "カフェオイルキナ酸類" },
      { "id": "n_methylpyridinium", "label_ja": "N-メチルピリジニウム" }
    ],
    "interpretation_ja": "湯量÷粉量が16を超えた実験では、調べた4成分の90%超が最初の抽出液へ移った。香り・味・全成分の90%を意味しない。"
  },
  "brewing_standard": {
    "source_id": "sca_gold_cup_2012",
    "extraction_yield_percent_min": 18,
    "extraction_yield_percent_max": 22,
    "quality": "certification_range",
    "interpretation_ja": "抽出収率は粉の乾燥重量から飲料へ溶けた固形分の割合。粉側に残る重量が、そのまま次の1杯へ溶ける量ではない。"
  },
  "fractionation": {
    "source_id": "batali_2020",
    "applicability": "single_brew_time_fractions_not_second_use",
    "protocol": {
      "coffee": "Colombian Huila Arabica, Agtron 54",
      "coffee_mass_g": 210,
      "water_volume_l": 3.8,
      "water_temperature_c": 91,
      "brew_description": "業務用ドリップ機で抽出液を30秒ごとに8分画",
      "trained_panelists": 12,
      "sensory_scale_min": 0,
      "sensory_scale_max": 100
    },
    "tds_endpoints": [
      { "fraction": 1, "seconds": "0–30", "tds_percent": 3.0, "quality": "reported_approximate" },
      { "fraction": 8, "seconds": "211–240", "tds_percent": 0.3, "quality": "reported_approximate" }
    ],
    "sensory_observations": [
      {
        "metric_id": "bitter",
        "label_ja": "苦味",
        "values": [
          { "fraction": 1, "seconds": "0–30", "value": 56.56 },
          { "fraction": 4, "seconds": "91–120", "value": 31.53 },
          { "fraction": 8, "seconds": "211–240", "value": 21.06 }
        ]
      },
      {
        "metric_id": "sour",
        "label_ja": "酸味",
        "values": [
          { "fraction": 1, "seconds": "0–30", "value": 55.89 },
          { "fraction": 4, "seconds": "91–120", "value": 27.64 },
          { "fraction": 8, "seconds": "211–240", "value": 11.47 }
        ]
      },
      {
        "metric_id": "astringent",
        "label_ja": "収れん感",
        "values": [
          { "fraction": 1, "seconds": "0–30", "value": 42.67 },
          { "fraction": 4, "seconds": "91–120", "value": 28.19 },
          { "fraction": 8, "seconds": "211–240", "value": 24.89 }
        ]
      },
      {
        "metric_id": "sweet",
        "label_ja": "甘味の知覚",
        "values": [
          { "fraction": 1, "seconds": "0–30", "value": 9.92 },
          { "fraction": 4, "seconds": "91–120", "value": 19.31 },
          { "fraction": 8, "seconds": "211–240", "value": 29.97 }
        ]
      }
    ],
    "interpretation_ja": "8分画の最初と最後を比べると、TDS、苦味、酸味、収れん感は低く、甘味の知覚は高かった。ただし全8区間が単調に変化したわけではなく、『後半は雑味だけ』という一般化を支持しない。"
  },
  "sequential_brewing": {
    "source_id": "maiyah_2026",
    "applicability": "sequential_brewing_residue_analysis",
    "protocol": {
      "species": ["Arabica", "Robusta"],
      "roast_levels": ["light", "medium", "dark"],
      "coffee_mass_g": 7,
      "water_volume_ml_per_cycle": 70,
      "water_temperature_c_min": 92,
      "water_temperature_c_max": 95,
      "brew_time_seconds_per_cycle": 20,
      "cycles": [1, 2, 3],
      "measured_material": "各サイクル後の使用済み粉を乾燥し、70%エタノールで抽出して分析"
    },
    "findings": [
      {
        "cycle": 1,
        "label_ja": "1回後",
        "finding_ja": "水溶性の生理活性成分は最初の抽出で最も大きく減った。"
      },
      {
        "cycle": 2,
        "label_ja": "2回後",
        "finding_ja": "さらに減少したが、追加サイクルによる変化は1回目より小さかった。"
      },
      {
        "cycle": 3,
        "label_ja": "3回後",
        "finding_ja": "カフェイン、クロロゲン酸、フェノール類は測定可能な量が残っていた。"
      }
    ],
    "interpretation_ja": "2回目・3回目にも成分がゼロとは限らないが、この研究は残った粉を分析したもので、2杯目・3杯目の濃さや摂取量を示さない。"
  },
  "limitations": [
    "市販ドリップバッグを同じ条件で2回・3回抽出し、各杯のTDS・カフェイン・官能を同時測定した全製品共通データではない。",
    "TDS、抽出収率、個別成分の移行率、官能強度は分母と測定方法が異なり、同じ割合として比較できない。",
    "8gの粉へ抽出収率18〜22%を当てはめた表示は、Gold Cup Standardを使った算術例であり、商品や入力値の実測ではない。",
    "粉量、湯量、温度、挽き目、焙煎、豆種、注ぎ方によって結果は変わる。",
    "使用済みの濡れた袋を保存して再利用する微生物学的安全時間は、採用研究では評価していない。"
  ]
}
